全文获取类型
收费全文 | 5806篇 |
免费 | 682篇 |
国内免费 | 1457篇 |
专业分类
化学 | 6408篇 |
晶体学 | 86篇 |
力学 | 60篇 |
综合类 | 60篇 |
数学 | 13篇 |
物理学 | 1318篇 |
出版年
2024年 | 24篇 |
2023年 | 102篇 |
2022年 | 136篇 |
2021年 | 245篇 |
2020年 | 262篇 |
2019年 | 247篇 |
2018年 | 223篇 |
2017年 | 218篇 |
2016年 | 287篇 |
2015年 | 247篇 |
2014年 | 246篇 |
2013年 | 506篇 |
2012年 | 346篇 |
2011年 | 355篇 |
2010年 | 315篇 |
2009年 | 382篇 |
2008年 | 356篇 |
2007年 | 386篇 |
2006年 | 325篇 |
2005年 | 337篇 |
2004年 | 325篇 |
2003年 | 264篇 |
2002年 | 217篇 |
2001年 | 190篇 |
2000年 | 195篇 |
1999年 | 186篇 |
1998年 | 150篇 |
1997年 | 126篇 |
1996年 | 130篇 |
1995年 | 111篇 |
1994年 | 86篇 |
1993年 | 96篇 |
1992年 | 76篇 |
1991年 | 47篇 |
1990年 | 27篇 |
1989年 | 16篇 |
1988年 | 33篇 |
1987年 | 17篇 |
1986年 | 22篇 |
1985年 | 22篇 |
1984年 | 14篇 |
1983年 | 5篇 |
1982年 | 9篇 |
1981年 | 12篇 |
1980年 | 7篇 |
1979年 | 9篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1974年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有7945条查询结果,搜索用时 15 毫秒
991.
P.A. Dowben Luis G. Rosa Carolina C. Ilie Jie Xiao 《Journal of Electron Spectroscopy and Related Phenomena》2009,174(1-3):10
We discuss the interactions of adsorbates with the organic ferroelectric copolymer poly(vinylidene fluoride (PVDF)–trifluoroethylene (TrFE)). Range of molecular adsorbates is discussed from the smaller polar molecules like water, which is small enough to both adsorb and absorb, to the larger macrocyclic metal–organic metal phthalocyanines. The changes in local dipole orientation may affect the strength of the coupling between adsorbate or absorbate and the copolymer poly(vinylidene fluoride–trifluoroethylene). The interface dipole interactions may also affect device properties. The dipole interactions are implicated at the interface between copper phthalocyanine and poly(vinylidene fluoride with trifluoroethylene) affecting the band offsets and the diode properties. 相似文献
992.
J. Barba-Ortega Clécio C. de Souza SilvaJ. Albino Aguiar 《Physica C: Superconductivity and its Applications》2009,469(14):852-856
Within the framework of nonlinear time dependent Ginzburg–Landau equations (TDGL) we study the properties of a mesoscopic superconducting film with both surfaces in contact with a thin superconducting layer at a higher critical temperature. The properties of the layer are taken into account by the de Gennes boundary conditions via the extrapolation length b. We assume that the magnetic field is parallel to the multilayer interfaces. We obtain magnetization curves and calculate the spatial distribution of the superconducting electron density using a numerical method based on the technique of gauge invariant variables. This work tests both the rectangular cross-section size and b limit for the occurrence of vortices in a mesoscopic sample of area dxxdy where dy = 80ξ(0) and dx varies discretely from 20ξ(0) to 3ξ(0). Our data also show a linear behavior of the magnetization curve and a power-law of order parameter modulus in limit b → 0-. 相似文献
993.
In this investigation, we have characterized the Na2SO4 using differential scanning calorimetry (DSC). It is well known that Na2SO4 exhibits five polymorphs. However, the experimental evidence for all five polymorphs has never been observed in DSC. In this
investigation, the five polymorphic transformations have been observed in heating cycle. Furthermore, the transition I–II
is observed, which is not reversible. In addition, phase transition temperature for V→IV and IV→III transition appears to
be much closed and may get unnoticed. 相似文献
994.
氯原子在Cu(111)表面的吸附结构和电子态 总被引:1,自引:1,他引:0
密度泛函理论(DFT)总能计算研究了不同覆盖度下氯原子在Cu(111)表面的吸附结构和表面电子态。计算结果表明,清洁Cu(111)表面自由能 为15.72 ,表面功函数φ为4.753eV。在1/4ML和1/3ML覆盖度下,每个氯原子在Cu(111)表面fcc谷位的吸附能分别等于3.278eV/atom和3.284eV/atom。在1/2ML覆盖度下,两个紧邻氯原子分别吸附于fcc和hcp谷位,氯原子的平均吸附能为2.631eV/atom。在1/3ML覆盖度下,fcc和hcp两个位置每个氯原子吸附能的差值约为2meV/atom,与正入射X光驻波实验结合蒙特卡罗方法得到结果(<10meV/atom)基本一致。在1/4ML、1/3ML和1/2ML覆盖度下,吸附后Cu(111)表面的功函数依次为5.263eV、5.275eV和5.851eV。吸附原子和衬底价轨道杂化形成的局域表面电子态位于费米能级以下约1.2eV、3.6eV和4.5eV等处。吸附能和电子结构的计算结果表明,氯原子间的直接作用和表面铜原子紧邻氯原子数目是决定表面结构的两个重要因素。 相似文献
995.
电荷补偿对Sr2SiO4:Dy3+材料发射光谱的影响 总被引:2,自引:1,他引:1
采用高温固相反应方法在空气中制备了Sr2SiO4:Dy3+发光材料.在365 nm紫外光激发下,测得Sr2SiO4:Dy3+材料的发射光谱为一多峰宽谱,发射峰分别位于486,575和665 nm处.研究了电荷补偿剂Li+,Na+和K+对Sr2SiO4:Dy3+材料发射光谱强度的影响,结果显示,不同电荷补偿剂下,随电荷补偿剂掺杂浓度的增大,Sr2SiO4:Dy3+材料发射光谱强度的演化趋势相同,即,Sr2SiO4:Dy3+材料发射峰强度先增大后减小,但不同电荷补偿剂下,材料发射峰强度最大处对应的补偿剂浓度不同,对应Li,Na+和K+时,浓度分别为4 mol%,3 mol%和3 mol%.同时,对研究结果进行了理论分析. 相似文献
996.
给出了优化小分子在团簇表面吸附结构的遗传算法.结合经验势函数,搜寻了水分子在(TiO2)n(n=3—6)团簇上可能的吸附方式;利用B3LYP/6-31G**方法对各种吸附结构进行了优化.结果表明水分子主要通过O原子以非解离方式吸附到团簇中配位数较低或位置比较凸出的Ti原子上.分子轨道分析表明,水分子与团簇之间的成键主要来自吸附位Ti原子3s3p轨道的贡献,水分子的轨道保持了气相水分子中的基本特征,但离域化程度增大
关键词:
2团簇')" href="#">TiO2团簇
2O吸附')" href="#">H2O吸附
遗传算法
DFT 相似文献
997.
对闭口碳纳米管(CNT)顶端分层掺氮及吸附不同数目水分子体系,运用第一性原理研究了有电场存在时的电子场发射性能.结果表明:掺氮并吸附水分子的CNT结构稳定;外电场愈强、水分子数愈多,体系态密度(DOS)向低能端移动幅度愈大且最高分子占据轨道(HOMO)/最低分子空轨道(LUMO)能隙愈小.吸附能,DOS/LDOS,HOMO/LUMO及其能隙分析一致表明,第三层氮掺杂CNT吸附不同数目水分子体系的场发射性能最佳.
关键词:
氮掺杂
水吸附
密度泛函理论
电子场发射 相似文献
998.
Mohamed Mokhtar Mohamed Ibrahim Mekkawy 《Journal of Physics and Chemistry of Solids》2003,64(2):299-306
The dc and ac conductivities as well as the dielectric constant () were measured for different zeolites encapsulated gold (AuCl3) samples at different temperatures (300-500 K) and various frequencies (5 kHz-1 MHz). The conductivity was found to change in the order Au/FSM-27>Au/NaY>Au/FSM-47. Sorbed water contained inside zeolites assists greatly the proton mobility (zeolite protons) and the ion mobility (Na+ and Au+) and hence enhance the electric conduction in the temperature range 300-373 K. Raising the temperature over 373 K induces dehydration effect that assists the metallic gold formation and thus a dramatic loss in conductivity was revealed. The conduction mechanism was expected to be partially ionic and partially electronic. The IR study showed that the exposure of Au zeolites to CO gas produced a characteristic band of Au+-CO at 2180 cm−1 that tends to decrease with temperatures and even vanishes at 376 K in favor of Au0-CO at 2128 cm−1. Similarly, a phase transition at 338 K, that occurs in the range 300-376 K, was confirmed by DTA to further emphasize the temperature regions of either Au+ cations (338 K) or Au0 (376 K) formation. 相似文献
999.
The microsurface adsorption–spectral correction (MSASC) technique has been applied to investigate the interaction of alkali blue 6B (AB6B) with cetyltrimethylammonium bromide (CTAB). The aggregation of AB6B on CTAB obeys the Langmuir isothermal adsorption. The aggregate was characterized by MSASC. For the monomer aggregate AB6B2CTAB formed, its binding constant is calculated to be K = 3.01·105 and its molar absorptivity to be 2.45·106 liters·cm–1 at = 690 nm. The adsorption has been used to carry out quantitative detection of cationic surfactant in samples. 相似文献
1000.
Medine Gavin M. Klabunde Kenneth J. Zaikovskii Vladimir 《Journal of nanoparticle research》2002,4(4):357-366
The thermodynamically favored reaction of solid strontium oxide with gaseous hydrogen sulfide is kinetically enhanced to a large degree by the use of higher surface area nanocrystalline SrO in the form of brush-like collections of metal oxide fibers. An unusual feature is that the reaction SrO + H2S SrS + H2O proceeds stoichiometrically at room temperature, but at higher temperatures the reaction efficiency goes down, apparently due to rapid temperature induced crystal growth of the nanocrystalline SrO. The samples studied vary in crystallite size from 20 to 27nm, while average particle size (nanocrystal aggregates) varies in the following order; aerogel prepared SrO (100nm) 相似文献